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(ZSM-5)Catalytic pyrolysis of tyres: influence of catalyst temperature


Two stage pyrolysis¨Ccatalysis of used tyres was undertaken to upgrade the derived oil to a highly aromatic oil suitable to be used as a chemical feedstock rather than a liquid fuel. The tyres were pyrolysed in a fixed bed reactor and the evolved pyrolysis gases were passed through a secondary fixed bed reactor containing zeolite catalyst. The pyrolysis reactor was maintained at 500 ˇăC and the influence of catalyst temperature between 430 and 600 ˇăC on the yield and composition of the derived oils was examined.
Pyrolysis of scrap tyres with zeolite USY

zeolite catalyst of ultrastable Y-type (USY) was investigated in the research of two staged pyrolysis¨Ccatalysis of scrap tyres. Scrap tyres were pyrolysed in a fixed bed reactor and the evolved pyrolysis gases were passed through a secondary catalytic reactor. The main objective of this paper was to investigate the effect of zeolite USY on the yield of products and the composition of derived oil. The influences of several parameters such as pyrolysis temperature, catalytic temperature, catalyst/tyre ratio, heating rate, etc. on the yield of the derived oil, char and gas were investigated. It showed that the increase of catalytic temperature and catalyst/tyre ratio resulted in high yield of gas at the expense of the oil yield.
Pyrolysis of waste tyres with zeolite USY and ZSM-5 catalysts
Pyrolysis of waste tyres was carried out with a two-stage bed reactor. The waste tyres were first pyrolysed in a fixed bed reactor, and then the evolved pyrolysis gases were passed through a secondary catalytic reactor filled with two types of zeolite catalysts, which were ultrastable Y-type (USY) and ZSM-5 catalyst. The catalytic temperatures were examined to determine their influence on the yield of product from the pyrolysis¨Ccatalyst of waste tyres.
 
 

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